|
TABLE
1. Gross Heating Values (GHV) and Net Heating Values (NHV)
| Fuel
Gas |
kcal/Nm³ |
kcal/kg |
|
|
GHV |
NHV |
GHV |
NHV |
| Hydrogen |
3050
|
2570 |
33889
|
28555 |
| Methane |
9530
|
8570
|
13284 |
11946 |
| Ethane |
16700
|
15300
|
12400
|
11350 |
| Ethylene |
15100 |
14200
|
12020
|
11270 |
| Natural
Gas from Campos |
10060
|
9090
|
16206
|
14642 |
| Natural
Gas from Santos |
10687
|
9672 |
15955
|
14440 |
| Natural
Gas from Bolivia |
9958
|
8993
|
16494
|
14896 |
| Propane |
24200
|
22250
|
12030
|
11080 |
| Propylene |
22400
|
20900
|
11700
|
10940 |
| n-Butane |
31900 |
29400
|
11830 |
10930 |
| iso-Butane |
31700
|
29200
|
11810
|
10900 |
| Butylene-1 |
29900
|
27900
|
11580
|
10830 |
| iso-Pentane
(liquid) |
- |
- |
11600
|
10730 |
| LPG
(average) |
28000
|
25775 |
11920
|
10997 |
| Acetylene |
13980
|
13490
|
11932
|
11514 |
| Carbon
Monoxide |
3014
|
3014
|
2411 |
2411 |
TABLE
2. Density and Specific Gravity
| Fuel
Gas |
Density |
Specific
Gravity |
|
(kg/Nm³) |
(air
= 1) |
| Air |
1,29 |
1,00 |
| Hydrogen |
0,09 |
0,07 |
| Methane |
0,72 |
0,56 |
| Ethane |
1,35 |
1,05 |
| Ethylene |
1,26 |
0,98 |
| Natural
Gas from Campos |
0,79 |
0,61 |
| Natural
Gas from Santos |
0,83
|
0,64 |
| Natural
Gas from Bolivia |
0,78 |
0,60 |
| Propane
|
2,01 |
1,56 |
| Propylene |
1,91 |
1,48 |
| n-Butane |
2,69 |
2,09 |
| iso-Butane |
2,68 |
2,08 |
| Butylene-1 |
2,58 |
2,00 |
| LPG
(average) |
2,35 |
1,82 |
| Acetylene |
1,17 |
0,91 |
| Carbon
Monoxide |
1,25 |
0,97 |
TABLE
3. Wobbe Index
| Fuel
Gas |
Upper
Wobbe Index |
Lower
Wobbe Index |
| |
(kcal/Nm³) |
(kcal/Nm³) |
| Hydrogen |
11528 |
9714 |
| Methane |
12735 |
11452 |
| Ethane |
16298 |
14931 |
| Ethylene |
15253 |
14344 |
| Natural
Gas from Campos |
12837 |
11597 |
| Natural
Gas from Santos |
13307 |
12043 |
| Natural
Gas from Bolívia |
12834 |
11591 |
| Propane |
19376 |
17814 |
| Propylene |
18413 |
17180 |
| n-Butane |
22066 |
20336 |
| iso-Butane |
21980 |
20247 |
| Butylene-1 |
21142 |
19728 |
| LPG
(average) |
20755 |
19106 |
| Acetylene |
14655 |
14141 |
| Carbon
Monoxide |
3060 |
3060 |
TABLE
4. Adiabatic Flame Temperature (gas, air and oxygen at 20ºC)
| Fuel
Gas |
Air
(ºC) |
Oxygen
(ºC) |
| Methane |
1957 |
2810 |
| Ethane |
1960 |
- |
| Propane |
1980 |
2820 |
| Butane |
1970 |
- |
| Hydrogen |
2045 |
2660 |
| Acetylene |
2400 |
3100 |
TABLE
5. Minimum Autoignition Temperature (fuel gas,air and oxygen at
atmospheric pressure)
| Fuel
Gas |
Air
(ºC) |
Oxygen
(ºC) |
| Methane |
580 |
555 |
| Ethane |
515 |
- |
| Propane |
480 |
470 |
| Butane |
420 |
285 |
| Carbon
Monoxide |
630 |
- |
| Hydrogen |
570 |
560 |
| Acetylene |
305 |
296 |
TABLE
6. Flammability Limits or Explosive Limits (fuel gas, air and
oxygen at 20ºC and at atmospheric pressure)
| Limits |
Lower
(%) |
Upper
(%) |
Lower
(%) |
Upper
(%) |
| Methane |
5,0 |
15,0 |
5,0 |
60,0 |
| Ethane |
3,0 |
12,4 |
3,0 |
66,0 |
| Ethylene |
2,7 |
36,0 |
2,9 |
80,0 |
| Propane |
2,8 |
9,5 |
2,3 |
45,0 |
| Propylene |
2,0 |
11,1 |
2,1 |
52,8 |
| Butane |
1,8 |
8,4 |
1,8 |
40,0 |
| Carbon
Monoxide |
12,0 |
75,0 |
- |
- |
| Hydrogen |
4,0 |
75,0 |
4,0 |
94,0 |
| Acetylene |
2,2 |
80
/ 85(*) |
2,8 |
93,0 |
| (*)
Different book references. |
|
TABLE
7. Flame Speeds
| Fuel
Gas |
Air |
Oxygen |
| |
(m/sec) |
(m/sec) |
| Methane |
0,4 |
3,9 |
| Propane |
0,45
/ 0,5 |
3,3
/ 3,9 |
| Butane |
0,35
|
3,3 |
| Acetylene |
1,46 |
7,6 |
| Hydrogen |
2,66
|
14,35 |
TABLE
8. Fundamental Combustion Equations
TABLE
9. Perfect Combustion with Air
| Fuel
Gas |
Air
Required |
Combustion
Products |
| |
(Nm³
air / Nm³ gas) |
(Nm³
c.p. / Nm³ gas) |
| Carbon
Monoxide |
2,40
|
2,90 |
| Methane |
9,62 |
10,62 |
| Acetylene |
12,02 |
12,52 |
| Ethylene |
14,42 |
15,42 |
| Ethane |
16,83 |
18,33 |
| Propylene |
21,36 |
23,13 |
| Propane |
24,04 |
26,04 |
| Butylene |
28,85 |
30,85 |
| Butane |
31,25 |
33,75 |
| Hydrogen |
2,40
|
2,90 |
TABLE
10. Perfect Combustion with Oxygen
| Fuel
Gas |
Oxygen
Required |
Combustion
Products |
| |
(Nm³
O2 / Nm³ gas) |
(Nm³
c.p. / Nm³ gas) |
| Carbon
Monoxide |
0,50 |
1,00 |
| Methane |
2,00
|
3,00 |
| Acetylene |
2,50 |
3,00 |
| Ethylene |
3,00
|
4,00 |
| Ethane |
3,50 |
5,00 |
| Propylene |
4,50 |
6,00 |
| Propane |
5,00 |
7,00 |
| Butylene |
6,00 |
8,00 |
| Butane |
6,50 |
9,00 |
| Hydrogen |
0,50 |
1,00 |
|